Light-driven kinetic resolution of α-functionalized carboxylic acids enabled by engineered fatty acid photodecarboxylase.Dawes, G. J. S. et al. 5 Chemical Vendors. In the reaction sequence, triolein is hydrolysed by the lipase from,Next, we addressed the low productivity issue as well as the need for two individual catalysts by constructing a co-expression system in.Despite the lower catalyst loading as compared to the experiment shown in Fig.In addition to the above-used fatty acid hydratases, a range of further fatty acid hydroxylating enzymes (e.g., linoleate 9S-lipoxygenase from,For the dihydroxylation of oleic acid, 5,8-diol synthase from.Overall, in this contribution we have demonstrated that secondary fatty alcohols can be obtained from unsaturated fatty acids using a cascade of fatty acid hydratase or diol synthase and fatty acid decarboxylase. 1 Structures Expand this section. as formate, acetate, propionate, and butyrate, as opposed to the IUPAC nomenclature methanoate, ethanoate, propanoate and butanoate. Dates: Modify: 2020-09-05. Deoxygenation of biobased molecules by decarboxylation and decarbonylation-a review on the role of heterogeneous, homogeneous and bio-catalysis.Engleder, M. et al. 2020R1A2B5B03002376).These authors contributed equally: Wuyuan Zhang, Jeong-Hoo Lee.Department of Biotechnology, Delft University of Technology, Van der Maasweg 9, 2629 HZ, Delft, The Netherlands,Wuyuan Zhang, Sabry H. H. Younes, Fabio Tonin, Peter-Leon Hagedoorn & Frank Hollmann,School of Chemical Engineering and Technology, Xi’an Jiaotong University, 710049, Xi’an, China,Department of Food Science & Engineering, Ewha Womans University, Seoul, 03760, Republic of Korea,Jeong-Hoo Lee, Yoonjin Baeg & Jin-Byung Park,Chemistry Department, Faculty of Science, Sohag University, Sohag, 82524, Egypt,Institute of Molecular Biotechnology, Graz University of Technology, Petersgasse 14, 8010, Graz, Austria.J.B.P., R.K. and F.H. In a first step the C=C-double bond is stereoselectively hydrated using oleate hydratases from,Envisioning a biobased chemical industry, there is an increasing interest in the transformation of biomass-derived starting materials into chemical building blocks,For example, with the discovery of the fatty acid decarboxylase OleT,Long-chain secondary alcohols, which may be active ingredients in cosmetic formulations,Fascinated by the synthetic possibilities offered by,The photoactivated carboxylic acid decarboxylase.We first drew our attention to the hydratase/decarboxylase cascade, which indeed proceeded as envisioned.Encouraged by this proof-of-concept, we further investigated the substrate scope of the photoenzymatic cascade reaction. Synthesen von trail-pheromonen der pharaoameise (.Saeki, A. et al. Fatty acids are molecules with a carboxylate COO– or COOH hydrophilic head, which is covalently linked to a hydrophobic tail of the form CH3–(CH2)n that may intercalate an unsaturated CH=CH group within its CH2 chain.
Peroxygenases en route to becoming dream catalysts. A route to convert fatty acids into hydrocarbons.Decomposition studies of different mixtures of NaOH and oleic acid.In this work, it was investigated the conversion of fatty acids into hydrocarbon based on the reaction with NaOH followed by a controlled thermal decomposition. Coconut Fatty Acid. & Girhard, M. Cytochrome P450 monooxygenases in biotechnology and synthetic biology.Wang, Y. et al. Evolving the promiscuity of,Joo, Y. -W. et al. Esters derived from the simplest carboxylic acids are commonly named according to the more traditional, so-called "trivial names" e.g. FTIR, Raman, UV–vis, XRD, TG-MS, SEM/TEM, CHN, GC–MS showed that precursors based on NaOH/oleic acid (molar ratios 0.7, 1.0, 1.5 and 2.0) decomposed at 550 °C to produce three fractions,We use cookies to help provide and enhance our service and tailor content and ads. Production of 10-hydroxystearic acid from oleic acid by whole cells of recombinant,Kang, W. -R. et al. The substrate scope of the current system is fairly broad giving access to enantiomerically pure alcohols from renewable starting materials. conceived the study, supervised the experimental work and data analysis and wrote the manuscript. A versatile approach to organic photovoltaics evaluation using white light pulse and microwave conductivity.Sorigué, D. et al.
Production of 5,8-dihydroxy-9(Z)-octadecenoic acid from oleic acid by whole recombinant cells of,Estupiñán, M. et al. Ester names are derived from the parent alcohol and the parent acid, where the latter may be organic or inorganic. Light-driven enzymatic decarboxylation of fatty acids.Zhang, W. et al.
-C. et al. Thank you for visiting nature.com. 4 Related Records Expand this section. W.Z., F.T., Y.B., S.H.H.Y.
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